Abstract
Nowadays, an efficient wastewater management involves the use of advanced treatment technologies able to decompose hardly
biodegradable compounds with reasonable costs at the lowest possible environmental impact. In our work we used one of the
most efficient advanced wastewater treatment, the Fenton reaction and its photo-assisted version. The hydrogen peroxide was the
oxidizer; despite its relatively high cost, its high activity in oxidizing of a large variety of organic persistent pollutants in the
presence of Fe3+ ions as catalyst, makes it an alternative which is worth to be considered even in practical medium scale systems.
The Fenton and photo-Fenton oxidation were performed using a model dye, the xanthene-type Rhodamine 6G, widely used in a
series of biotechnology applications, but having major drawbacks when released in natural water flows, mainly mutagen and
carcinogen effects. Therefore, a parametric case study was performed in order to define the optimal operating parameters (the pH
value, the hydrogen peroxide concentration and the iron catalyst concentration). The oxidative degradation of Rhodamine 6G by
Fenton reaction was more effective when combined with UV irradiation. Each parameter of the oxidative treatment is essential
for the color and TOC removal. The optimal values found for the total color degradation and mineralization of the dye were as
follows: 16 ppm Fe3+, 100 ppm H2O2 and pH of 4.5.